Determination of chloride by gravimetric analysis. Determination Of Chloride Gravimetric and Volumetric Method Comparison ABSTRACT The gravimetric analysis 2022-10-28

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Gravimetric analysis is a method of chemical analysis in which the mass of an element or compound is measured to determine its quantity. One of the common methods for gravimetric analysis is the determination of chloride ions, which are anions (negatively charged ions) with the chemical formula Cl-. Chloride ions are present in a variety of compounds, including sea water, brines, and many inorganic and organic substances. In this essay, we will discuss the determination of chloride ions by gravimetric analysis, including the principle behind the method, the experimental procedure, and the potential sources of error.

The principle behind the gravimetric determination of chloride ions is based on the formation of a precipitate with a known composition. Chloride ions can be quantitatively precipitated as silver chloride (AgCl) by adding a solution of silver nitrate (AgNO3) to a sample containing chloride ions. The reaction between silver nitrate and chloride ions is shown below:

AgNO3 + Cl- → AgCl + NO3-

The mass of the precipitate, AgCl, can then be measured and used to calculate the mass of chloride ions in the sample. The mass of chloride ions is calculated using the following equation:

Mass of chloride ions (g) = Mass of AgCl (g) x (atomic weight of Cl / formula weight of AgCl)

The experimental procedure for the gravimetric determination of chloride ions involves several steps. First, a known volume of the sample containing chloride ions is taken and diluted with water to a known concentration. Next, a solution of silver nitrate is added to the sample until all of the chloride ions are precipitated as silver chloride. The precipitate is then collected by filtration, washed with water to remove any excess silver nitrate, and dried in an oven at a temperature of 110°C for at least 1 hour. The mass of the dried precipitate is then measured using a balance and used to calculate the mass of chloride ions in the sample.

There are several potential sources of error in the gravimetric determination of chloride ions. One common source of error is incomplete precipitation of the silver chloride, which can occur if the concentration of silver nitrate is too low or if the reaction time is not sufficient. Another potential source of error is the loss of the precipitate during the filtration and washing steps, which can occur if the precipitate is not properly collected or if it dissolves in the wash water. Finally, errors can also occur in the measurement of the mass of the precipitate, which can be influenced by factors such as the sensitivity of the balance and the accuracy of the temperature control in the oven.

In conclusion, the gravimetric determination of chloride ions is a widely used method for the quantitative analysis of chloride ions in a variety of compounds. The method is based on the formation of a precipitate with a known composition, and the mass of the precipitate is used to calculate the mass of chloride ions in the sample. However, there are several potential sources of error in the method, including incomplete precipitation, loss of the precipitate during the filtration and washing steps, and errors in the measurement of the mass of the precipitate.

Lab 4 Gravimetric Determination of webapi.bu.edu

determination of chloride by gravimetric analysis

NaCl + AgNO3 AgCl s + NaNO3 Equation 1 Table 1-Standard NaCl titration trials Trial NaCl weight End Point Real Moles NaCl Conc. Pour out the 6 M NH3 into the waste container then wash crucibles with deionized for 6-8 times. . If the sample is not dry, put in oven for at least 2 hours at 120°. Introduction The purpose of this lab was to determine the percentage of chloride in an unknown soluble salt sample through a gravimetric method known as precipitation gravimetry. Dissolve, dilute to the mark with nanopure water, and mix. All these salts seem to have a significantly higher percent than my unknown salt.


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Gravimetric Determination of Chloride

determination of chloride by gravimetric analysis

Thus, it is possible to calculate the Chloride content by the direct proportion rule. The solution without the precipitate was slowly poured into the filter. Then, the precipitate was washed in the beaker with a few milliliters of the washing solution, and the liquid was again decanted into the filter crucible. Then, the precipitate was dried at constant weight at 110 ºC in order to make sure that no amount of moisture is left that could affect the final dry weight of the precipitate. See Figure 4 below. Weigh the filter papers plus AgCl and calculate the mass of AgCl. Add approximately 100 mL of deionized water and 2-3 mL of 6 M HNO3 to each sample.

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(PDF) Determination of chloride Ion Concentration by Gravimetric

determination of chloride by gravimetric analysis

Hence, the errors encountered from the measurements conducted were estimated using propagation of uncertainty. If the coagulate did go through, the results would be lower. Table 7- Relation of experimental error between methods. The unknown is weighed and dissolved in water. Keep the filter paper folded.

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Gravimetric Analysis of a Chloride Salt

determination of chloride by gravimetric analysis

However, it is clear that gravimetry has better precision and accuracy in the results compared to the titrimetric method, this is due to a smaller number of steps in this methodology, which leads to a smaller amount of errors in relation to the titrimetric analysis4. INTRODUCTION Titration and gravimetry are two branches of analytical chemistry used to quantify an analyte through chemical reactions. Another possible error source of error that may have occurred involves incomplete drying to the sample due to the temperature that the oven was set at. Once the stoichiometric point is reached, the plate ions Ag+ are in excess. The precision of my results was 5. White or silver color. Each crucible was rinsed with six to eight portion distilled water.

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LAB Report Gravimetric Determination of Chloride

determination of chloride by gravimetric analysis

Weighing the sample is done by difference. Final product The precipitate had coagulated and a light purple color on the outside. Set up vacuum filtration once again using the 500 mL filtering flask, crucible holder with funnel, vacuum tube, and vacuum. Determination Of Chloride Gravimetric and Volumetric Method Comparison ABSTRACT The gravimetric analysis and the titrimetric precipitation method were performed to assess the chloride content in samples of sodium chloride and an unknown sample. The Annals of Occupational Hygiene, 33 3 , 331-337. In this laboratory, the electrode used is specific for chloride ion. Try to get as much precipitate as possible into each wash using the rubber policeman.

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Determination of Chloride Content in an Unknown Salt

determination of chloride by gravimetric analysis

Fort Worth: Saunders College Pub. Inside of the tube is a reference solution, which contains a known and fixed concentration of analyte Cl - solution. Avoid eye and skin contact. Set up a vacuum filtration using the 500 mL filtering flask crucible holder with funnel, vacuum, and vacuum tube. Chloride electrode left with the fill hole closed middle and open right. The copper II chloride crystals were blue in colour, shown in Figure 1 below. Can you eliminate indeterminate errors from your experiment? The titrimetric method resulted in a mass percent of 28.

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Gravimetric Analysis Of A Chloride Salt [6klzjqgdmeng]

determination of chloride by gravimetric analysis

In this method, an adsorption indicator is used such as dichlorofluorescein. Error Experimental %E Tritrimetric Analisys %E Gravimetric Analisys 0,9040% 0,4963% Table 7 shows the values resulting from the calculation of experimental errors. Again, the number of moles of silver nitrate found should equal the number of moles of chloride. Dilute to the mark with nanopure water and mix. If the solution level is very low or the bottle is empty, prepare additional solution. Background Information Quantitative analysis is that aspect of-analytical chemistry concerned with determining how much of one or more constituent is present in a particular sample of material. If the solid had been washed with pure water, then the layer would have been disturbed causing the particle to shrink in size.

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Free Essay: Gravimetric Determination of chloride in a soluble sample

determination of chloride by gravimetric analysis

Through heating and the high concentration of the ions, the silver chloride coagulated to a desirable size that could be filtered and washed with nitric acid through a previously weighed crucible. The precipitate can be collected on a filter paper, dried, and weighed. The colloid obtained is made of silver chloride as primary adsorption layer and nitrate ions make up the counter-ion layer to stabilize the system. The objective was to accurately and precisely convert the unknown sample containing the chloride analyte to another known solid, silver chloride. This order of addition is critical to ensure complete precipitation of the chlorides.

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